Supercatalysis by Superexchange
نویسندگان
چکیده
منابع مشابه
Superexchange-driven magnetoelectricity in magnetic vortices.
We demonstrate that magnetic vortices in which spins are coupled to polar lattice distortions via superexchange exhibit an unusually large linear magnetoelectric response. We show that the periodic arrays of vortices formed by frustrated spins on kagome lattices provide a realization of this concept; our ab initio calculations for such a model structure yield a magnetoelectric coefficient that ...
متن کاملLattice and superexchange effects in doped CMRmanganites
We report on the influence of the lattice degrees of freedom on charge, orbital and spin correlations in colossal magnetoresistance (CMR) manganites. For the weakly doped compounds we demonstrate that the electron-phonon coupling promotes the trapping of charge carriers, the disappearance of the orbital polaron pattern and the breakdown of ferromagnetism at the CMR transition. The role of diffe...
متن کاملStudy of Magnetic Superexchange in diluted Systems
model the covalency-mixing parameters, λσ and λπ, the electron spin transfer coefficients, ƒi (i=σ, π, s ), and the total charge, C, transferred from ligand to the chromium ions, are evaluated. The variation of bσσ and bσπ with x agree with the passage of the system from ferromagnetic to antiferromagnetic order. For the compound presenting re-entrant behaviour ( 58 . 0 45 . 0 ≤ ≤ x ), fs exhibi...
متن کاملTheory of anisotropic superexchange in insulating cuprates.
Spin-orbit corrections to superexchange are calculated using the method of Moriya [T. Moriya, Phys. Rev. 120 91, (1960)] for two of the insulating parent compounds of the cuprate superconductors: (1) La2−xNdxCuO4 where the CuO6 octahedra forming each Cu-O layer are tilted in staggered fashion about an axis which depends on x and temperature; and (2) YBa2Cu3O6+x (x ∼ 0.4) where the Cu-O layers f...
متن کاملEvidence for energy transfer induced by superexchange in LaF 3 : Pr3+
2014 Direct measurement of fluorescence quenching rates for various Pr3+ pairs in weakly doped LaF3 are reported. Since few pairs only are quenched, the transfer mechanism is short range. From the rate values, the shape of the fluorescence decay for heavily doped samples is predicted. The good agreement with the observed decay proves the interest of the connection between microscopic and macros...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: The Journal of Physical Chemistry C
سال: 2016
ISSN: 1932-7447,1932-7455
DOI: 10.1021/acs.jpcc.6b09099